WebPhosphorene, an atomic layer of phosphorus, was realized by the mechanical exfoliation from the layered crystal of black phosphorus (BP) in 2014.1) It is a single component two-dimensional (2D) crystal following graphene and silicene. In contrast to graphene, which is a 2D zerogap conductor, phosphorene is a 2D semiconductor with a finite band gap. Phosphorene 2D materials are composed of individual layers held together by van der Waals forces in lieu of covalent or ionic bonds that are found in most materials. There are five electrons on 3p orbitals of phosphorus atom, thus, giving rise to sp hybridization of phosphorus atom within phosphorene structure. Monolayered phosphorene exhibits the structure of a quadrangular pyramid be…
Strain-engineered direct-indirect band gap transition and its …
WebOct 20, 2014 · Importantly, the varied band gap and robust direct band gap character in few-layer phosphorene provides a basis to fabricate multi-junction solar cells which can more … WebJun 11, 2024 · More importantly, the direct band gap can be dramatically tuned by either the in-plane strain or the coverage ratio of adsorbates, which enables monolayer blue phosphorus to efficiently adsorb visible light. The mechanism of strain effect and surface adsorption on band gap tuning was deeply discussed. first start
Phosphorene – The two-dimensional black phosphorous: …
WebApr 11, 2024 · With its widely tunable band gap, strong in-plane anisotropy, and high carrier mobility, phosphorene is at the center of numerous fundamental studies and applications spanning from... WebMay 13, 2014 · The band gaps of PNRs can be strongly modulated by a transverse electric field, showing a metal-insulator-transition (MIT), while PNRs with a longitudinal gate i.e., under a perpendicular... WebJan 30, 2024 · The quantum Monte Carlo (QMC) method is applied to obtain the fundamental (quasiparticle) electronic band gap Δf of a semiconducting two-dimensional phosphorene whose optical and electronic... first star sherwin williams paint